Chemistry

Energy and Reaction Behavior flashcards

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What is an exothermic reaction?Endothermic and Exothermic Changes
One transferring energy to surroundings overall.
What is an endothermic process?Endothermic and Exothermic Changes
One absorbing energy from surroundings overall.
What is activation energy?Endothermic and Exothermic Changes
The pathway barrier to reaction.
What does a catalyst change?Endothermic and Exothermic Changes
Pathway barrier and often rate, not net endpoint energy difference.
What sign is ΔH for an endothermic system?Endothermic and Exothermic Changes
Positive under the stated constant-pressure convention.
What does a simple calorimeter measure?Endothermic and Exothermic Changes
Temperature change used to estimate heat transfer.
Why must the system be identified?Endothermic and Exothermic Changes
It determines the sign and boundary of energy transfer.
How are rate laws obtained?Reaction Rates
From experimental evidence.
What is activation energy?Reaction Rates
The energy barrier associated with a reaction pathway.
How does a catalyst affect a pathway?Reaction Rates
It provides an alternative with a lower activation barrier.
What is dynamic equilibrium?Equilibrium Foundations
Equal forward and reverse rates with continuing reactions.
What is Q?Equilibrium Foundations
A ratio describing the current reaction composition.
What does Q>K predict?Equilibrium Foundations
Net reverse change toward equilibrium.